Investigation of thermal conductivity and thermal performance of heat pipes by structurally designed copolymer stabilized ZnO nanofluid


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Sep 21, 2023

Investigation of thermal conductivity and thermal performance of heat pipes by structurally designed copolymer stabilized ZnO nanofluid

Scientific Reports volume 13, Article number: 14219 (2023) Cite this article Metrics details The present study concentrated on estimating the thermal conductivity, stability, efficiency, and

Scientific Reports volume 13, Article number: 14219 (2023) Cite this article

Metrics details

The present study concentrated on estimating the thermal conductivity, stability, efficiency, and resistance of a heat pipe for heat exchangers, which were essential for many industrial applications. To achieve this, copolymer of amphiphilic poly (styrene-co-2-Acrylamido-2-methylpropane sulfonic acid) poly (STY-co-AMPS) was synthesized by free radical polymerisation technique. The dispersant were used for homogeneous solution and stabilization of ZnO nanofluids. The effect of dispersant on the thermal conductivity of nanofluids was analysed using a KD2 pro thermal property analyser. There is a significant increase in fluid conductivity had a nonlinear relationship with the volume fraction. The maximum enhancement was observed at an optimized concentration of dispersant at 1.5 vol%. Same time, the influence of dispersant agent on the thermal conductivity of nanofluids were compared with linear polyelectrolytes. Further, the experimental values were compared to the existing classical models based on the reasonable aggrement, the prepared nanofluids were employed as a working medium. The conventional screen mesh heat pipe and the temperature distribution to the thermal resistance of the heat pipe was investigated experimentally. The result shows, optimum concentration of dispersants on nanoparticles exhibits an enhanced heat efficiency as compared with the base fluids. Further, the thermal resistance and temperature distribution show decreased behaviour by increasing the particle volume fraction and dispersant concentration.

From the past two decades, energy storage, energy transmission, and heat generation are the major research domain to which 90% of the global energy budget were allotted. The rapid developments were taken up into advanced thermal materials and technological research. Hence, there is a need to improve the thermo-physical properties of the working fluids which may lead to enhancing the heat transfer performance of the devices. Majorly, engine oil, ethylene glycol and water were widely used as conventional fluids for heat transfer because of their low thermal conductivity, which affects the performance the heat transfer devices. Since the heat pipe is a two-phase heat transfer device which transfers heat with a very low-temperature drop from one place to another. Because of their effective cooling efficiency, these are widely used in various heat transfer applications. The heat pipe is a common cooling system in many thermal applications because the working fluid circulates through a capillary pressure gradient. The phase transition and evaporation/condensation of the working fluid cause substantial variation in heat transfer characteristics The effectiveness of heat pipe is based on the quality/dimension of the material, fluid properties and wick structures1. The thermal application includes such as solar systems2, gas sensing3, electronic cooling4, optoelectronics5, aerospace6, and heat exchangers7,8.

For heat transfer applications, nanofluids were used as working fluids which may overcome the drawback of conventional fluids. The stable dispersion of thermal nanofluids is required to fulfil the potential and realize the industrial standards9. The main drawback of NPs would be phase-separated and precipitated out of the fluids. During the heat-transfer process, the aggregated nanofluids would cause clogging and abrasion issues in particular microelectronic systems10. Achieving dispersion of thermal nanofluids is one of the greatest challenges and many approaches have been attempted which includes the addition of surface charges / utilizing chemical surface modification with surfactants. ultrasonic treatment, mechanical stirring and so on.

Many researchers have been attempted to improve the thermal performances of nanofluids in that, Kang et al.11 investigated the effect of silver nanofluids on a sintered heat pipe. According to their findings, there is a decrease in wall temperature input power of 30–50 W. Furthermore, nanofluids as a working medium in heat pipes evidenced higher thermal performance of up to 70 W when compared to water as a base fluid12. Similarly, Rosari et al.13 investigated the thermal conductivity and heat pipe thermal performance of ZnO-Ethylene glycol-based nanofluids at lower particle volume fractions. In their observation, the temperature distribution and thermal resistance of the heat pipes decreases by increasing the particle volume fraction and crystalline size. Whereas, Jian et al.14 reported the thermal performance comparison of oscillating heat pipes (OHP) with SiO2 -water and Al2O3- water nanofluids at a mass concentration of nanoparticles (0–0.6 wt% SiO2 and 0–1.2 wt% Al2O3). It is observed that, the change in surface conditions at the condenser and evaporator is mainly due to different particle, which affect the thermal performance or deterioration of heat pipes15. Furthermore, a comparative study of sintered and mesh wick heat pipes on CuO nanofluids was performed by Kumaresan et al.16. In their study, the sole effect of sintered wick heat pipes shows enhanced thermal performance and thermal resisitance of heat pipes as compared to the mesh wick heat pipes at 70 W.

Suresh et al.17 prepared a hybrid nanofluids Al2O3–Cu/DI water (90:20 weight proportion) using a dispersant—sodium lauryl sulphate (SLS). Experimental, thermal conductivity and viscosity of hybrid nanofluids were investigated and maximum thermal conductivity was found to be 12.11% at 2% volume concentration. Hamidesh et al.18 developed functionalized CNT-water nanofluids by using oxidising agents to improve the cooling capacity of electronic devices. In the thermosyphon, nanofluids with a highly functionalized sodium moiety performed better in terms of higher thermal efficiency and lower thermal resistance. Nanofluids easily get agglomerated due to their high specific surface area, maintaining stability has become a difficult issue19. Furthermore, the aggregated nanofluids tend to settled out, which degrades the thermal properties of the nanofluids20. In most cases, a high quantity of surfactants needs to be added to get a good stability, resulting in increased thermal conductivity and viscosity. However, the high viscosity of nanofluids needs more power to transport the fluid from one point to another, which hinders the use of these nanofluids in practical applications. To overcome the stability issues, polymer dispersants were used as a stabiliser to improve the long-term stability of the nanofluids. Based on the literature review, less work has been done on polymer dispersants for thermal conductivity and heat pipe experimental techniques.

Recently, functionalized copolymers received significant importance due to their wide range of properties provided by tuning/replacing the structural features such as sulphonyl, carboxylic, amides, aldehydes, anhydrides, soluble polymeric side chains and so on. This creates an effective electrostatic barrier that prevents the agglomeration of the particles and enhances dispersion stability21. The surface properties of NPs can be modified by amide functionalized copolymers by changing their solution properties, such as surface charge and colloidal stability22.

In the present work, amphiphilic poly (STY-co-AMPS) copolymer as a dispersant was synthesized. AMPS is a hydrophilic sulphonic acid acrylic monomer that is highly reactive and exhibits good thermal stability23. The functionalized copolymer has a hydrophobic backbone i.e. Styrene moiety which leads to easy adsorbing onto the cationic surface of the NPs. On the other hand, hydrophilic AMPS moiety creates an electrostatic effect for the proper dispersion of NPs in the fluids. Incorporation of STY and AMPS moieties in the amphiphilic polymer structure is proven to be suitable for the dispersion of NPs into aqueous media. Hydrophilic highly functionlized sulfonyl (–SO3), amide (–NH2) and hydroxyl (–OH) groups have a high degree of ionization leads to improve the dispersion properties of the NPs. We demonstrate the potential of water-soluble amphiphilic polymers containing –SO3 group as dispersants for uniform dispersion of NPs in the fluids. This approach provides a convenient way to stabilize the nanofluids using a modified technique in the presence of structurally designed functional copolymers on the thermo-physical properties of ZnO nanofluids for heat transfer applications.

The chemicals [(AMPS—2-Acrylamido-2-methylpropane sulfonic acid), (AIBA—Azobisisobutyronitrile), (STY—Styrene)] were purchased from sigma Aldrich with 99% purity and styrene was used after the purification process. The solvents (Diethyl ether and Dimethylformamide) were purchased from Merck, India used as received. Double distilled water was used to create the dispersions.

The free radical polymerizations of STY and AMPS are carried out in a typical three-necked round-bottom flask outfitted with a reverse chiller, an N2 gas inlet tube, a stirrer, and a thermistor at 70 °C to 80 °C with AIBN as the radical initiator in an N2 atmosphere. The mixture is stirred for about 24 h. Further, diethyl ether was used to precipitate the produced copolymer, which was then dried under vacuum at 60 °C to a consistent weight. The scheme of the reaction is represented in Fig. 1. FTIR, 1H, and 13C NMR spectroscopy were used to determine the structure and compositions of the copolymers.

Schematic representation for the synthesis of Poly (STY-co-AMPS) copolymer.

The synthesis and characterisation of ZnO NPs were described in the previous publication24,25. The same ZnO NPs were used in this present study. To ensure even particle dispersion, a determined volume of ZnO NPs was added to the base fluid and sonicated for an hour. The resulting mixture was then ultrasonicated for nearly 2 h at ambient temperature using an ultrasonicator (Make: Dakshin Ultrasonics, India) having a fixed frequency of 22 kHz and output power of 240 W at room temperature for approximately 2 h. The same process was used to create a second batch of nanofluids that contained various STY-co-AMPS copolymer chains of an amphiphilic polymer as a dispersant.

To ensure uniform blending of the dispersant in the base fluids, the different concentrations of dispersant were first dispersed in the base fluid and constant stirring for an hour. Following the dispersant-base fluid mixture, the measured volume concentration of NPs was added. This was followed by the same process as mentioned before. The thermo-physical characteristics of water-based ZnO nanofluids were then examined.

KD2 Pro ((Decagon Devices, USA) thermal property analyzer was used to evaluate the thermal conductivity of ZnO nanofluids. It includes a 60 mm probe that acts as a heat source as well as a temperature sensor. To operate and carry out the measurements, the probe is attached to a microcontroller. The gadget was calibrated using the glycerine that comes with the equipment to determine the experiment’s accuracy margin.

As illustrated in Fig. 2, the experimental setup includes a heat pipe, cooling system, data collection, and computer. Heat pipes with an outside diameter of 19.5 mm and a length of 350 mm were designed in order to compare predicted thermal efficiency with experimental evidence. The heat pipe contains four layers of 100 mesh copper wire screen wick (0.009 mm wire diameter). To completely saturate the wick, 12 cc of working fluid is loaded onto the heat pipe after it has been constructed.

Graphical view (a) Experimental setup (b) Position of the thermocouple.

In the current experiment, dispersant-stabilised ZnO nanofluids are used as the working fluid. The heater section has a maximum power capability of 1000 W. The evaporator draws its energy from an AC power supply. To prevent thermal resistance between the surfaces of the heater and evaporator, a high thermal conductivity paste is applied. To prevent heat loss between the evaporator and heater surface, a 40 mm thick fibreglass material with a thermal conductivity of 0.04 W/m-K is utilised. The heat pipe’s condenser is made of acrylic material, the chiller delivers a constant flow rate of 320 mL/min of cooling water into the cooling jacket at a constant temperature of 25 ± 0.5 °C.

The flow rate of the cooling water is measured by a flow metre. The cooling water flow rate is found to be 2% uncertain. The temperatures of the heat pipe walls and the cooling water at the condenser’s inlet and outlet are measured with an accuracy of 0.1 °C using OMEGA T-type thermocouples. The heat pipe is positioned horizontally. The heat input used in the experiment’s ranges from 50 to 400 W. Using an Agilent data logger, steady state temperature measurements are made during the experiment for intervals of 30 s. The steady state temperature measurements are then saved in the computer for further processing and date reduction.

The heat input in the current study is estimated using the voltmeter and ammeter values as follows:

The amount of heat transferred to the coolant water can be calculated from the difference in temperature between the inlet and outlet water, taking into account the water mass flow rate and specific heat as well26,

where \(\Delta T=\)(\({T}_{out}\) − \({T}_{in}\)), \({T}_{out}\) and \({T}_{in}\) are the temperatures of the cooling fluid at its exit and inlet, respectively. m and Cp are the mass flow rate and heat capacity of the coolant, respectively.

Evaporator heat transfer coefficient of the heat pipes27 are calculated using Eq. (3)

In order to evaluate a heat pipe’s thermal performance, it is especially important to consider the temperature drops between the evaporator and condenser. The heat pipe’s overall thermal resistance is described as follows:

where \(\Delta T={T}_{e}-{T}_{c}\) , \({T}_{e}\) and \({T}_{c}\) are the average evaporator and condenser wall temperatures respectively. The thermal resistance of the evaporator and condenser are calculated using Eqs. (5) and (6)28.

The average wall temperature in the vapor line was considered as saturation or vapor temperature \({T}_{vap}\).

The thermal efficiency of the heat pipes are calculated by based on the law of thermodynamics29,30 using following Eq. (7).

where \({\eta }_{th}-\mathrm{thermal effciency }, \frac{{Q}_{out}}{{Q}_{in}}\)—heat out and heat input respectively. The calculate values are tabulated in the Table 1.

Each parameter as measured error. After the above calculations, the uncertainities in the measurement heat transfer coefficient and total thermal resistance were calculated using the following Eqs. (7–10)27,28 .

Uncertainity in heat transfer rate is calculated as

where \(\Delta m\)—Error in the mass flow rate measurement, \(\Delta t\)—Error in the temperature difference of cooling fluid and \(\frac{\Delta Q}{Q}\) represents the uncertainity present in the estimation of the heat transfer rate.

Uncertainity in heat flux is calculated as

Uncertainity in the thermal resistance is calculated by

where the \({\Delta T}_{hp}\) and \(\frac{\Delta R}{R}\) are the error in the temperature difference and uncertainity in the thermal resistance of the heat pipes respectively.

Uncertainity in heat transfer coeffiecient is calculated as

The uncertainties in the measurement of heat flux, thermal resistance and measurement are presented in Tables 2 and 3. It is seen that the uncertainities in the measurements of heat flux, total resisitance and heat transfer coefficients as the heat input increases from 50 to 400 W.

For the comparison of the effective thermal conductivity of the nanofluids, numerous mathematical models have been brought forth31,32. To calculate the thermal conductivity of ZnO-nanofluids, we used the Hamilton Crosser, Pak and Cho, and Timofeeva models (Eqs. 13, 14, and 15), and we compared the results to experimental observations. ZnO NPs are discovered to have a thermal conductivity of 23.413 W/m-K.

According to the Hamilton and Crosser (H–C) model (1962)33,34 created to determine a two-phase mixture’s effective thermal conductivity,

where \({\mathrm{k}}_{\mathrm{p}}\)—Thermal conductvity of the NPs, \(\mathrm{\varphi }\)—NPs volume fraction, \({\mathrm{k}}_{\mathrm{bf}}\)—Thermal conductvity of base fluids, sphericity is defined as the ratio of the surface area of a sphere with a volume equal to that of the particle to the surface area of the particle, and n is the empirical shape factor determined by n = 3/\(\varphi \). The H–C model estimates the thermal conductivity ratio, k nf/k bf, for values of ranging from 0.5 to 1.5.

For Al2O3 and TiO2 nanofluids, Pak and Cho35 created a thermal conductivity model, which was written as

The effective medium hypothesis was proposed by Timofeeva et al.36 to determine the thermal conductivity ratio for strongly conducting spherical particles. The model makes the unrealistic assumption that the particles are stationary.

In Fig. 3. FTIR for poly (STY-co-AMPS) copolymer: Characteristic peaks at 2919–3000 cm−1 (Ar –CH of benzene ring), 1436 and 1406 cm–1(vibration of –C–C bonds in the benzene ring), 3418 and 1665 cm–1 (–NH stretching and C=O stretching), 1406 cm–1(–C–N stretching) and 1016 cm–1 (stretching vibration of SO3H). In Fig. 4. 1H NMR (400 MHz, DMSO): δ = 2.32–2.56 (–CH and –CH2), 7.05–7.96 (Ar –CH), 1.42 (CH3 in side chain –C(CH3)2), 1.25–1.89 (–CH and –CH2 for AMPS), 2.68 (–CH2–SO3H), 6.15–6.78 (broad, NH amide) and 8.22 (–OH) for AMPS. 13C NMR (400 MHz, DMSO): δ = 125.61–129.19 (p-, o-, m-, Ar –CH), 168.18 (C=O anhydride and amide, overlapping), 51.54–53.93 (C–(CH3)2), 25.62–42.54 (–CH–CH2), 58.05 (CH2–SO3H) are respective signals confirms the formation of copolymer it is shown in Fig. 5.

FTIR spectrum for poly (STY-co-AMPS) copolymer.

1H NMR spectrum for poly (STY-co-AMPS) copolymer.

13C NMR spectrum for poly (STY-co-AMPS) copolymer.

A quantitative assessment of the particle size distribution was obtained using DLS analysis. A freshly prepared, diluted sample was used for the analysis, which was carried out at 25 °C. Figure 6a. depicts the ZnO nanofluid’s particle size distribution. The polydispersity index (ratio of the mass-weighted average particle diameter to the number-weighted average particle diameter), as determined by DLS analysis, is 1.001, and the number-averaged particle size is 95 nm. The observed particle size is significantly bigger than the desired nanoparticle size (50 nm), suggesting that thermodynamically stable clusters of particles may have formed. This is primarily due to the adsorbed layer of amphiphilic copolymer dispersants on the cationic surface of the nanofluids, which results in larger particle diameter. Figure 6b. displays the poly (STY-co-AMPS) stabilised ZnO nanofluid particle size distribution, which is found to be 221 nm, and the polydispersity index, which is 0.364.

DLS images for (a) ZnO nanofluid (b) Dispersant stabilized ZnO nanofluid.

The polydispersity index value less than one indicates better homogeneity and less clustering. It implies that the dispersants played an active role in the dispersion of ZnO nanofluids due to electrostatic hindrance produced between the copolymer’s adsorbed layer and the NPs in the suspension. It is further confirmed using zetapotential data.

The zeta potential was used to assess the stability of NPs dispersion in the base fluids shown in Fig. 7. depicts the zeta potential value of dispersant stabilised ZnO nanofluids with and without dispersant. The zeta potential value for ZnO nanofluids in the absence of dispersant was − 6.78 mV in Fig. 7a, and the potential value slightly shifted from negative to positive with the addition of dispersant, i.e. 50.1 mV in Fig. 7b. It is because an adsorbed layer of poly (STY-co-AMPS) copolymer dispersants on the surface of ZnO NPs creates an effective electrostatic barrier between the particles, ensuring greater stability and dispersibility37.

Zeta potential images for (a) ZnO nanofluid (b) Dispersant stabilized ZnO nanofluid.

Figure 8 shows photographs of 1 wt% ZnO nanofluids without and with (STY-co-AMPS) copolymer as dispersant at various concentrations ranging from 0.5 to 2.0 vol%. Due to the strong attraction between the NPs, ZnO nanofluids begin to aggregate and settle at the bottom of the vial after 45 min of preparation. The dispersant-stabilised ZnO nanofluids are stable for 10 days at all concentrations. Furthermore, polymer stabilised nanofluids begin phase separation after 15 days of preparation and complete sedimentation is observed after 20 days, with the exception of 1.5 vol% dispersant stabilised nanofluids, which is stable for nearly one month due to sufficient adsorbed molecules creating a strong electrostatic repulsion between NPs and is considered optimal concentration. While the dispersant concentration increased to 2.0 vol%, the stability of nanofluids decreased due to an increase in the adsorbed molecules in the solution, which causes flocculation38.

Sedimentation Photographs of with and without dispersant stabilized ZnO nanofluids.

The thermal conductivity of ZnO nanofluids at a various volume fractions of dispersant and NPs are represented in Fig. 9. The best dispersion and thermal conductivity enhancement of nanofluids are observed at 1.0 vol% ZnO NPs and 1.5 vol% STY-co-AMPS copolymer as a dispersant due to proper dispersion leads to more heat transfer. At 0.931 W/m-K, 1 wt% ZnO nanofluids stabilised by 1.5 vol% dispersant offered the highest thermal conductivity enhancement as shown Fig. 9a.

Thermal conductivity of ZnO nanofluids (a) At various volume fractions (b), different temperatures along with error bars (c) Comparison between experimental and a theoretical model.

Figure 9b depicts the investigation into the effect of temperature on the thermal conductivity of ZnO nanofluids, with error bars on the graph indicating the standard deviation over subsequent measurements. Thermal conductivity increases with increasing temperature and gradually decreases with increasing polymer dispersant concentration due to overadsorption of polymer dispersants, which inhibits heat transfer as well as Brownian motion of NPs. The ionic interaction of the highly functionalized hydrophobic styrene moiety adsorbed on the cationic surface of the ZnO NPs and the hydrophilic ionizable sulfonal (\({\mathrm{SO}}_{3}^{-}\)) and hydroxyl (–OH) functionlized AMPS moiety extended into the fluids suspension creates an effective electrostatic barrier between the NPs in the base fluids, promoting homogeneous dispersion and stabilisation which inturn enhaces the heat transfer24,38.

Figure 9c provides a comparison between the theoretical and experimental thermal conductivity values of ZnO nanofluids. The results revealed that the experimental thermal conductivities are having a slight agreement with the Hamilton and Crosser model and Timofeeva model at lower particle volume fraction (0.5%). However, the Pak and Cho Model over predicts the experimental results.

The uncertainty measurement of thermal conductivity of nanofluids experimental results was determined using the instrument and precision error caused by the deviation in the experimental dataset. KD2 Pro has a 5% instrument error in measuring thermal conductivity39. The weighing scale has a precision of 0.01 g. The following yields the uncertainty of the experiment data40 .

where \({\mu }_{B}, {\mu }_{p}, {t }_{v, p}\) and SD are bias error, precision or random error in the measurement with p% probability, weighing function \(\vartheta \) degree of freedom and sample standard deviation respectively.

where keff and kf represent uncertainty at p% probability, including both instrument and precision errors associated with the measured effective thermal conductivity and thermal conductivity of nanofluids, respectively. Finally, the uncertainty in effective thermal conductivity and TCR (thermal conductivity ratio) was discovered to be between 0.5 and 4.5%.

In Fig. 10. Based on the thermal conductivity measurements, the formulated nanofluid was charged into the heat pipe and its performance was evaluated. The overall thermal resistance of the heat pipes between the 0° and 90° angles at various heat inputs (50–400 W) was measured to estimate the effect of inclination angle on the thermal performance of the heat pipe using water as the base fluid, as shown in Fig. 10a. The lowest thermal resistance of the base fluid was observed at 45° inclination angle, which is considered as a base inclination angle for the total thermal resistance of the ZnO nanofluids for various particle volume fractions (0.5–1.5%) at 50–400 W heat inputs in Fig. 10b. The thermal resistance of the heat pipe is reduced by up to 1.0 vol%. Then, it gradually increases with increasing vol% of ZnO nanofluids, owing to NP agglomeration. At all inclination angles of the ZnO nanofluids at lower vol% (0.5–1.0), the total thermal resistance gradually decreases with heat inputs up to 250 W and then varies with heat input increases.

(a) Optimization of inclination angle for base fluids (b) Total thermal resistance v/s particle volume fraction at various heat inputs (c) Variation of total thermal resistance with various heat inputs.

To investigate the heat transfer performance of the dispersant stabilized nanofluids experiments are carried out and compared with and without stabilized ZnO nanofluids and base fluids as represented in Fig. 10c. As a result, the thermal resistance of the ZnO nanofluids is higher than that of dispersant stabilized ZnO nanofluids. Initially, the thermal resistances of heat pipes using base fluids with and without ZnO nanofluids showed high thermal resistance at lower heat inputs and rapidly decreases with corresponding increase in heat inputs from 50 to 400 W44. According to Hopkins et al.44, this tendency for thermal resistance to vary with heat input is a common feature of heat pipes. Equation (4) is used to calculate the thermal resistance of the heat pipes. Because of the longer hydrophilic AMPS chain length, polymer stabilised nanofluids have higher thermal resistance than ZnO nanofluids, resulting in a decrease in heat transfer.

In the Fig. 11. depicts the thermal conductivity of heat pipe enhancement for various heat inputs. The improvement could be attributed to the deposition of NPs in the wicking mesh. According to the FESEM images, the coating layer on the screen mesh wick may aid in increasing the capillary effect of the wick structure. Surface wettability can be improved by lowering the contact angle and increasing the roughness of the wick surface, which raises the critical heat flux41. Recently, Nandy Putra et al.42 reported that the primary cause of the improvement in the thermal performance of the heat pipes utilising nanofluids was the creation of a thin coating at the screen mesh wick of the evaporation zone. Since there is less deposition when using a dispersant, the thermal conductivity starts to fall sharply at 100 W. The heat pipe tends to migrate closer to the dry-out situation since its maximum heat transmission capacity is reached at about 100 W. The temperature differential between the evaporator surface and the vapour rises as a result of this partial dry-out situation, which tends to lower the heat transfer coefficient43,44. The maximum effective thermal conductivity observed at 38% in 150 W, 29% in 100 W and 11% in 100 W for ZnO nanofluids, Polymer stabilized nanofluids and base fluids respectively.

Effective thermal conductivity of nanofluids with respect to heat input.

Figure 12 shows photographs of ZnO nanofluids with and without dispersants taken before and after the heat pipe experiment. The photography clearly shows that the dispersant-stabilised nanofluids were more stable after the experiment than the ZnO nanofluids.

(a) Before and after heat pipe experiment of ZnO nanofluids (b) Before and after heat pipe experiment of poly (STY-co-AMPS) copolymer stabilized ZnO nanofluids.

The thermal resistance at the evaporator is estimated with and without NPs deposition in order to demonstrate the impact of Ps deposition in the wick on heat pipe performance.

where \({\mathrm{R}}_{\mathrm{e}}\)—Resistance in evaporator, \({\mathrm{d}}_{\mathrm{o},\mathrm{ w}} , {\mathrm{d}}_{\mathrm{i},\mathrm{ w}}\) are the wall outer and inner diameter, \({\mathrm{d}}_{\mathrm{o},\upomega }, {\mathrm{d}}_{\mathrm{i},\upomega }\) are the wick outer and inner diameter, \({\mathrm{l}}_{\mathrm{e}},\) length of evaporator section, \({\mathrm{k}}_{\mathrm{wall}}\) and \({\mathrm{k}}_{\mathrm{wick}}\) are the thermal conductivity of wall and wick respectiviely.

The combination of a nanofluid and wick has an effective thermal conductivity44 estimated as

The following equation is used to determine the porosity of the multiple later of the screen mesh wick (\(\varphi \))28.

Then the porosity of the single layer of wick (\({\mathrm{\varphi }}_{1})\) is calculated as45

In the Fig. 13. illustrates the measured with and without deposition of NPs at the heat pipe’s evaporator section for varied heat inputs. The evaporator segment of the heat pipe with deposited wick mesh has lower resistance than the corresponding section without deposited wick mesh, it is discovered might be the formation of thin porous layer by the NPs in the fluids.

Resistance at the evaporator.

As a result, heat pipes’ ability to transport heat is reduced. Because of the adsorption of a polymer layer on the surface of the NPs, ZnO nanofluids have lower thermal resistance than dispersant-stabilised nanofluids.

After all the experiments are completed, heat pipes are cut open and the wick structure was analysed using FESEM shown in Fig. 14. The FESEM images for the ZnO nanofluids stabilized with and without addition of copolymer as dispersant after the heat pipe experiment as shown in Fig. 14a,b. It was found that the NPs are deposited on the wick structure in both cases of nanofluids. However, copolymer stabilised nanofluid showed less deposition than the other one. It clearly indicates that the porous layer on the surface results in more heat transfer. As compared 1 vol% of ZnO nanofluids showed higher heat transfer than 1 vol% of ZnO nanofluids stabilized by 1.5 vol%.

FESEM images for with and without dispersant stabilized ZnO nanofluids (a) poly (STY-co-AMPS) copolymer stabilized 1 vol% of ZnO nanofluids (b) 1 vol% of ZnO nanofluids after heat pipe experiment.

The thermal conductivities of poly (STY-co-AMPS) copolymer stabilised ZnO nanofluids with a lower concentration of ZnO NPs were experimentally investigated in the current work. In addition, an experiment was performed using the dispersant stabilized nanofluids as working fluids in wick heat pipes in order to measure the thermal resistance at various heat inputs.

The structurally designed poly (STY-co-AMPS) copolymer was synthesized by a free radical polymerisation reaction and confirmed by FT-IR, 1H-NMR and TGA. ZnO NPs were prepared by microwave irradiation method followed by the preparation of ZnO nanofluids by dispersing different volume fractions of NPs (0.5–1.5 vol%) and dispersant concentration (0.5–2.0 vol%).

The optimized concentration of dispersants showed the enhanced thermal performance of the nanofluids. The maximum thermal conductivity 0.931 W/m-K was observed at 1 vol% of ZnO nanofluids stabilized by 1.5 vol% dispersant.

The effective thermal conductivity enhancement found to be 38%, 29% and 11% for ZnO nanofluids, polymer stabilized ZnO nanofluids and base fluids respectively.The experimental result was compared with the theoretical models, the H–C model is a good corresponding agreement with the values.

Further, the corresponding nanofluids used as working fluid in heat pipe experiments in order to evaluate the thermal resistance of the heat pipe at various temperature distributions is a nonlinear relationship with the volume fraction and dispersant concentration. The maximum uncertainity is found to be 5.41%.

The decrease in the thermal resistance of the heat pipe with an increase in the concentration of the dispersant is due to adsorbed layer on the surface of the NPs. The dispersant-stabilized nanofluids exhibited thermal stability after the heat pipe experiment. This confirms that the polymer is stable at high-temperature operation it may be used as a coolant for heat transfer applications.

All data generated or analysed during this study are included in this published article [and its supplementary information files].

Area [m2]

Heat of vaporization [J/kg-K]

Length [m]

Mass flow rate [kg/s]

Thermal conductivity [W/m-K]

Heat flux [W/m2]

Heat transfer rate [W]

Resistance [°C/W]

Number of the layer of the wick

Crimping factor (1.05)

Mesh number

Temperature [\(^\circ \mathrm{C}]\)

Temperature difference between the vapor and condenser

Temperature difference between the outlet and inlet of the coolant

Porosity of multilayer wick

Porosity of the single layer wick

Thickness (m)










Sharma, S. K. & Mital, S. Preparation and evaluation of stable nanofluids for heat transfer application: A review. Exp. Therm. Fluid Sci. 79, 202–212. (2016).

Article CAS Google Scholar

Khairnasov, S. M. & Naumova, A. M. Heat pipes application to solar energy systems. Appl. Sol. Energy 52, 47–60. (2016).

Article Google Scholar

Navarrete, È. et al. Sensors and actuators B: Chemical WO3 nanowires loaded with cobalt oxide nanoparticles, deposited by a two-step AACVD for gas sensing applications. Sens. Actuators B. Chem. 298, 126868. (2019).

Article CAS Google Scholar

Jouhara, H., Chauhan, A., Nannou, T., Almahmoud, S. & Delpech, B. Heat pipe based systems - Advances and applications. Energy 128, 729–754. (2017).

Article Google Scholar

Kumar, S. S., Venkateswarlu, P., Rao, V. R. & Rao, G. N. Synthesis, characterization and optical properties of zinc oxide nanoparticles. Int. Nano Lett. (2013).

Article Google Scholar

Shukla, K. N. Heat pipe for aerospace applications—An overview. J. Electron. Cool. Therm. Control 5, 1–14. (2015).

Article ADS CAS Google Scholar

Jouhara, H. et al. Experimental and theoretical investigation of a flat heat pipe heat exchanger for waste heat recovery in the steel industry. Energy 141, 1928–1939. (2017).

Article Google Scholar

Nishikawara, M. & Nagano, H. Optimization of wick shape in a loop heat pipe for high heat transfer. Int. J. Heat Mass Transf. 104, 1083–1089. (2017).

Article Google Scholar

Yu, F. et al. Dispersion stability of thermal nano fluids. Prog. Nat. Sci. Mater. Int. 27, 531–542. (2017).

Article CAS Google Scholar

Pavithra, K. S., Yashoda, M. P. & Prasannakumar, S. Synthesis, characterisation and thermal conductivity of CuO-water based nanofluids with different dispersants. Part. Sci. Technol. (2019).

Article Google Scholar

Kang, S., Wei, W., Tsai, S. & Huang, C. Experimental investigation of nanofluids on sintered heat pipe thermal performance. Appl. Therm. Eng. 29, 973–979. (2009).

Article CAS Google Scholar

Raja, M., Vijayan, R., Dineshkumar, P. & Venkatesan, M. Review on nanofluids characterization, heat transfer characteristics and applications. Renew. Sustain. Energy Rev. 64, 163–173. (2016).

Article CAS Google Scholar

Saleh, R., Putra, N., Purbo, S. & Nata, W. Experimental investigation of thermal conductivity and heat pipe thermal performance of ZnO nano fluids. Int. J. Therm. Sci. 63, 125–132. (2013).

Article CAS Google Scholar

Qu, J. & Wu, H. Thermal performance comparison of oscillating heat pipes with SiO2/water and Al2O3/water nanofluids. Int. J. Therm. Sci. 50, 1954–1962. (2011).

Article CAS Google Scholar

Poplaski, L. M., Benn, S. P. & Faghri, A. Thermal performance of heat pipes using nanofluids. Int. J. Heat Mass Transf. 107, 358–371. (2017).

Article CAS Google Scholar

Kumaresan, G., Venkatachalapathy, S., Godson, L. & Wongwises, S. Comparative study on heat transfer characteristics of sintered and mesh wick heat pipes using CuO nanofluids. Int. Commun. Heat Mass Transf. 57, 208–215. (2014).

Article CAS Google Scholar

Suresh, S., Venkitaraj, K. P., Selvakumar, P. & Chandrasekar, M. Synthesis of Al2O3–Cu/water hybrid nanofluids using two step method and its thermo physical properties. Colloids Surf. A Physicochem. Eng. Asp. 388, 41–48. (2011).

Article CAS Google Scholar

Sardarabadi, H., Heris, S. Z., Ahmadpour, A. & Passandideh-fard, M. Experimental investigation of a novel type of two-phase closed thermosyphon filled with functionalized carbon nanotubes/water nanofluids for electronic cooling application. Energy Convers. Manag. 188, 321–332. (2019).

Article CAS Google Scholar

Lee, S. M., Yeh, W. L., Wang, C. C. & Chen, C. Y. The study on the conductivity of styrene-maleic anhydride copolymer electrolytes based on poly(ethylene glycol)400 and LiClO4. Electrochim. Acta 49, 2667–2673. (2004).

Article CAS Google Scholar

Bang, I. C. & Kim, J. H. Thermal-fluid characterizations of ZnO and SiC nanofluids for advanced nuclear power plants. Nucl. Technol. 5450, 16–27. (2017).

Article Google Scholar

Xia, G., Jiang, H., Liu, R. & Zhai, Y. Effects of surfactant on the stability and thermal conductivity of Al2O3/de-ionized water nanofluids. Int. J. Therm. Sci. 84, 118–124. (2014).

Article CAS Google Scholar

El-mahdy, G. A., Atta, A. M. & Al-lohedan, H. A. Synthesis and evaluation of poly (Sodium 2-Acrylamido-2-Methylpropane Sulfonate-co-Styrene)/magnetite nanoparticle composites as corrosion inhibitors for steel. Molecules 19, 1713–1731. (2014).

Article CAS PubMed PubMed Central Google Scholar

Ohtake, T., Ito, H., Horiba, K. & Toyoda, N. Synthesis of water-soluble polymeric surfactants bearing sulfonic acid groups and the effects of hydrophilic components on the rheology and dispersive properties of dye dispersions. ACS Appl. Polym. Mater. 4, 8556–8563. (2022).

Article CAS Google Scholar

Pavithra, K. S., Yashoda, M. P. & Srinivas, S. P. Viscosity and thermal conductivity of ZnO–water-based nanofluids stabilized by grafted SMA-g-MPEG comb-shaped copolymer for heat transfer applications. Iran. Polym. J. (2020).

Article Google Scholar

Pavithra, K. S. Effect of microwave irradiation power for the morphological changes of ZnO nanoparticles, in IOP Conference Series: Materials Science and Engineering, vol. 577, 012120 (IOP Publishing, 2019).

Noie, S. H., Heris, S. Z., Kahani, M. & Nowee, S. M. Heat transfer enhancement using Al2O3/water nanofluid in a two-phase closed thermosyphon. Int. J. Heat Fluid Flow 30, 700–705. (2009).

Article CAS Google Scholar

Solomon, A. B., Ramachandran, K., Asirvatham, L. G. & Pillai, B. C. Numerical analysis of a screen mesh wick heat pipe with Cu/water nanofluid. Int. J. Heat Mass Transf. 75, 523–533. (2014).

Article CAS Google Scholar

Solomon, A. B. et al. Application of bio-wick in compact loop heat pipe. Appl. Therm. Eng. 169, 114927. (2019).

Article CAS Google Scholar

Heris, S. Z., Salehi, H. & Noie, S. H. The effect of magnetic field and nanofluid on thermal performance of two-phase closed thermosyphon. Int. J. Phys. Sci. 7, 534–543. (2012).

Article CAS Google Scholar

Taylor, P., Using, T. & Water, S. M. Improvement in heat transfer of a two-phased closed thermosyphon using silver-decorated MWCNT/Water. J. Dispers. Sci. Tech. (2013).

Article Google Scholar

Sundar, L. S., Singh, M. K. & Sousa, A. C. M. Thermal conductivity of ethylene glycol and water mixture based Fe3O4 nanofluid. Int. Commun. Heat Mass Transf. 49, 17–24. (2013).

Article CAS Google Scholar

Murshed, S. M. S., Leong, K. C. & Yang, C. Thermophysical and electrokinetic properties of nanofluids – A critical review. Appl. Therm. Eng. 28, 2109–2125. (2008).

Article CAS Google Scholar

Cyanamid, A. Two-component systems. Ind. Eng. Chem. Fund. 1, 187–191. (1959).

Article Google Scholar

Nayak, M. K. et al. Interfacial layer and shape effects of modified Hamilton’s Crossers in entropy optimized Darcy -Forchheimer flow. Alex. Eng. J 60, 4067–4083. (2021).

Article Google Scholar

Taylor, P. et al. Hydrodynamic generation and heat transfer study of dispersed fluids with submicron metallic oxide. Therm. Energy (2013).

Article Google Scholar

Timofeeva, E. V. et al. Thermal conductivity and particle agglomeration in alumina nanofluids: Experiment and theory. Phys. Rev. (2007).

Article Google Scholar

Choudhary, R., Khurana, D., Kumar, A. & Subudhi, S. Stability analysis of Al2O3/water nanofluids. J. Exp Nanosci. 12, 140–151. (2017).

Article CAS Google Scholar

Nagpal, K. et al. Significance of hydroxyl groups on the optical properties of ZnO nanoparticles combined with CNT. Nanomaterials 12, 3546. (2022).

Article CAS PubMed PubMed Central Google Scholar

Banasali, S. et al. Enhanced thermal conductivity of Cu nanofluids: The effect of filler geometry. ACS Appl. Mater. Interfaces 9, 18925–18935. (2017).

Article CAS Google Scholar

Sharifpur, M., Tshimanga, N., Meyer, J. P. & Manca, O. Experimental investigation and model development for thermal conductivity of α-Al2O3-glycerol nanofluids. Int. Commun. Heat Mass Transf. 85, 12–22. (2017).

Article CAS Google Scholar

Zhang, W., Du, Z., Wang, W. & Wang, T. Synthesis and aggregation behaviour of grafted maleic acid copolymers. J. Colloid Interface Sci. 374, 187–196. (2012).

Article ADS CAS PubMed Google Scholar

Putra, N., Septiadi, W. N., Rahman, H. & Irwansyah, R. Thermal performance of screen mesh wick heat pipes with nanofluids. Exp. Therm. Fluid Sci. 40, 10–17. (2012).

Article CAS Google Scholar

Heris, S. Z. et al. Rheological behavior of zinc-oxide nanolubricants rheological behavior of zinc-oxide nanolubricants. J. Disper. Sci. Tech. (2013).

Article Google Scholar

Godson, L., Nimmagadda, R. & Wongwises, S. Heat transfer performance of screen mesh wick heat pipes using silver–water nanofluid. Int. J. Heat Mass Transf. 60, 201–209. (2013).

Article CAS Google Scholar

Solomon, A. B., Ramachandran, K. & Pillai, B. C. Thermal performance of a heat pipe with nanoparticles coated wick. Appl. Therm. Eng. 36, 106–112. (2012).

Article CAS Google Scholar

Maydanik, Y. F. Loop heat pipes. Appl. Therm. Eng. 25, 635–657. (2002).

Article Google Scholar

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Authors are greatful to Manipal Institute of Technology, MAHE, Manipal and Centre for Research in Material Science & Thermal Management, Karunya University, Coimbatore for providing the research facility.

Department of Chemistry, Research Centre, GM Institute of Technology, Davanagere, 577006, India

K. S. Pavithra

Department of Physics, Bapuji Institute of Technology, Davanagere, 577006, India

Vinay Parol

Micro and Nano Heat Transfer Laboratory, Department of Mechanical Engineering, Centre for Research in Material Science and Thermal Management, Karunya Institute of Technology and Sciences, Coimbatore, India

A. Brusly Solomon

Department of Chemistry, Manipal Institute of Technology, MAHE, Manipal, 576104, India

M. P. Yashoda

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All authors reviewed the manuscript.

Correspondence to K. S. Pavithra or M. P. Yashoda.

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Pavithra, K.S., Parol, V., Brusly Solomon, A. et al. Investigation of thermal conductivity and thermal performance of heat pipes by structurally designed copolymer stabilized ZnO nanofluid. Sci Rep 13, 14219 (2023).

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Received: 30 December 2022

Accepted: 27 July 2023

Published: 30 August 2023


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